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Aliases are distribution lists for the Release management workflow. Only Administrators can create Aliases and assign other users or Teams to an alias. Specifically, an Administrator needs the Manage users and teams global permission in order to create aliases and assign other users or teams to an Alias.

To navigate to your Aliases settings in Onshape, click on your Account user icon (Account user icon) in the top right corner of your Onshape window. This opens a dropdown menu. Click Company/Classroom/Enterprise settings.

Click Aliases in the list on the left side of the page:

Enterprise settings: Aliases

See Understanding Aliases for information on using Aliases.